Beryllium subphthalocyanines self-assembling properties
نویسندگان
چکیده
منابع مشابه
Self-assembling subnanometer pores with unusual mass-transport properties.
A long-standing aim in molecular self-assembly is the development of synthetic nanopores capable of mimicking the mass-transport characteristics of biological channels and pores. Here we report a strategy for enforcing the nanotubular assembly of rigid macrocycles in both the solid state and solution based on the interplay of multiple hydrogen-bonding and aromatic π-π stacking interactions. The...
متن کاملSynthesis and spectroscopic properties of chiral binaphthyl-linked subphthalocyanines.
Chiral binaphthyl-linked subphthalocyanines (SubPcs) (1) have been prepared by the cyclotrimerization reaction of a phthalonitrile linked with (R)- and (S)-2,2'-binaphthyl in the presence of BCl3, and characterized by various spectroscopies including NMR, electronic absorption, CD, and MCD, as well as electrochemistry.
متن کاملAxially diethylaminophenoxypropanoxy substituted new subphthalocyanines: synthesis and electropolymerization properties.
The treatment of boron(III) subphthalocyanine chloride with 1,3-bis[3-(diethylamino)phenoxy]propan-2-ol 2 and 2,3-bis[3-(diethylamino)phenoxy]propan-1-ol 4 in toluene gave the corresponding axially substituted boron(III) subphthalocyanine compounds 3 and 5. The novel axially diethylaminophenoxypropanoxy substituted subphthalocyanines were characterized by standard spectroscopy methods. The elec...
متن کاملSelf-Assembling Robots
One of the grand challenges of robotics is the design of robots that are adaptive and self-sufficient. This can be crucial for robots exposed to environments that are unstructured (in space and time) or not easily accessible for a human operator, such as the inside of a blood vessel, a collapsed building, the deep sea, or the surface of another planet.Modular reconfigurable robots are among the...
متن کاملSelf-Assembling Dynamical Hierarchies
This paper addresses the open problem of assembling multilevelled hierarchical structure. It presents a model of an infinitely-levelled, self-assembling dynamical hierarchy which arises from the interaction of geometric primary elements with a fixed complexity. A formal description of the presented hierarchy is derived. This quantifies the relative compression achieved by describing the system ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 2016
ISSN: 0008-4042,1480-3291
DOI: 10.1139/cjc-2016-0283